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The concept of atoms and molecules; laws of chemical combination; mole concept; chemical formulae, balanced chemical equations, concentration in terms of mole fraction, molarity, molality and normality. 
Gaseous, liquid and solid states; absolute scale of temperature, ideal gas equation; kinetic theory of gases, average, root mean square and most probable velocities and their relation with temperature; law of partial pressures; vapour pressure; surface tension and viscosity; classification of solids, crystalline state; seven crystal systems (only cell parameters a, b, c, , , and close packed structure of solids - only cubic). 
Atomic structure: Rutherford model, Bohr model, quantum numbers, electronic configuration of elements (upto atomic number 36), Aufbau principle, Pauli's exclusion principle, and Hund's rule. 
Periodicity of properties of elements: classification of elements into s, p, and d block; periodicity in properties with respect to atomic and ionic radii, ionisation energy, electron affinity, electronegativity, oxidation state, metallic and non-metallic character and trends in reactivity. 
Bonding and molecular structure: Lewis structures; orbital overlap and covalent bond; hybridisation involving s and p and d orbitals only; co-ordinate covalent bond, ionic bond, hydrogen bond; molecular shapes; linear, angular, planar, pyramidal, tetrahedral, and octahedral. 
Energetics: Ist law of thermodynamics; Internal energy; enthalpy; Hess's law; heat of reaction, fusion, and vaporisation. 
Chemical equilibrium: chemical equilibria; law of mass action, reaction quotient; equilibrium constant; dependence on concentration; temperature and pressure, solubility product, common ion effect. 
Electrochemistry: Electrochemical cells and cell reactions; standard electrode potential and electrochemical series; emf of a galvanic cell. 
 Preparation and properties of the following compounds: Oxides, hydroxides, carbonates, bicarbonates, chlorides and sulphates of sodium, potassium, magnesium and calcium, alumina, aluminium chloride and alums, hydrogen peroxide; carbon: oxides and carbides; nitrogen; oxides; oxyacids and ammonia; phosphorous: oxides and oxyacids (meta- nd orthophosphoric acids); Boron: diborane; silicon: silicates; sulphur: oxides, sulphurous and sulphuric acids, sodium thiosulphate and hydrogen sulphide; halogens: hydrohalic acids, oxyacids of chlorine, bleaching powder. 
Preparation and properties of the following compounds: Ferrous sulphate, ferric chloride, Mohr's salt, ferric oxide, copper sulphate, oxide and sulphate of zinc. 
Principles of qualitative analysis: Group I to V excluding interfering radicals. 
Ores and minerals: Commonly occurring ores of iron, copper, lead, magnesium and aluminium. 
Extractive metallurgy (Chemical principles and reactions only; industrial details excluded): Carbon reduction method (iron), self reduction method (copper and lead), electrolytic reduction method (magnesium and aluminium). 
Concepts of hybridisation of carbon, sigma and pi-bonds. Resonance. 
Homologous series, structural and geometrical isomerism, optical isomerism of compounds containing one asymmetric centre only. IUPAC nomenclature of simple organic compounds (hydrocarbons and mono functional compounds only). 
Inductive and resonance effects on acidity and basicity of acids and bases respectively. 
Polarity and inductive effects in alkyl halides. Reactive intermediates produced during homolytic and heterolytic bond cleavage. Formation, structure and stability of Alkyl carbocations and free radicals. 
Physical properties of alkanes (mp, bp and density), combustion and halogenation of alkanes. Preparation of alkanes by Wurtz coupling and decarboxylation reaction. 
Structure and physical properties of alkenes and alkynes (bp, density, dipole moment), acidity of alkynes. Preparation of alkenes and alkynes by elimination reaction. Electrophilic addition reaction of alkenes with Br2 HBr, HOCl. Reactions of alkynes: Metal acetylides. 
Benzene: structure and aromaticity. Electrophilic substitution reactions; bromination, nitration, sulfonation (orientation excluded). Phenols: acidity, electrophilic reaction (halogenation, nitration and sulphonation). 
Characteristic reactions of the followings: Alcohol (esterification, dehydration and oxidation). Reaction of alcohols with sodium, phosphorous halides, ZnCl2/Conc. HCl. Alkyl halides (nucleophilic substitution reactions). Aldehydes and ketones (oxidation, reduction, oxime and hydrazone formation). Carboxylic acids (formation of esters, acid chlorides and amides).

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

The concept of atoms and molecules

1 laws of chemical combination

 2 mole concept

 3 chemical formulae, balanced chemical equations, concentration in terms of mole fraction, molarity, molality and normality. 

 

Thermodynamics

Gaseous, liquid and solid states;

 absolute scale of temperature, ideal gas equation;

 kinetic theory of gases, average, root mean square and most probable velocities and their relation with temperature;

 law of partial pressures; vapour pressure; surface tension and viscosity; classification of solids, crystalline state; seven crystal systems (only cell parameters a, b, c, , , and close packed structure of solids - only cubic). 
Energetics:

 Ist law of thermodynamics; Internal energy; enthalpy; Hess's law; heat of reaction, fusion, and vaporisation. 

 

Atomic structure:

Rutherford model, Bohr model,

quantum numbers, electronic configuration of elements (upto atomic number 36), Aufbau principle, Pauli's exclusion principle, and Hund's rule. 
Periodicity of properties of elements: classification of elements into s, p, and d block; periodicity in properties with respect to atomic and ionic radii, ionisation energy, electron affinity, electronegativity, oxidation state, metallic and non-metallic character and trends in reactivity. 
Bonding and molecular structure: Lewis structures; orbital overlap and covalent bond; hybridisation involving s and p and d orbitals only; co-ordinate covalent bond, ionic bond, hydrogen bond; molecular shapes; linear, angular, planar, pyramidal, tetrahedral, and octahedral. 

 

Chemical equilibrium:

 chemical equilibria; law of mass action, reaction quotient; equilibrium constant; dependence on concentration; temperature and pressure, solubility product, common ion effect. 

 

Electrochemistry:

 Electrochemical cells and cell reactions; standard electrode potential and electrochemical series;

 emf of a galvanic cell. 

 

Chemical kinetics:

Rates of chemical reactions;

 order of reaction;

rate constant;

effect of concentration and temperature (excluding Arrhenius equation). 
Isolation/preparation and properties of the following non-metals:

 Nitrogen, phosphorous, oxygen, sulphur,

 fluorine, chlorine, bromine and iodine. Properties of allotropes of carbon (graphite and diamond only);

 preparation and properties of zone. 

 

For Practical purpose: -

Preparation and properties of the following compounds:

 Oxides, hydroxides, carbonates, bicarbonates, chlorides and sulphates of sodium, potassium, magnesium and calcium, alumina, aluminium chloride and alums, hydrogen peroxide; carbon: oxides and carbides; nitrogen; oxides; oxyacids and ammonia; phosphorous: oxides and oxyacids (meta- nd orthophosphoric acids); Boron: diborane; silicon: silicates; sulphur: oxides, sulphurous and sulphuric acids, sodium thiosulphate and hydrogen sulphide; halogens: hydrohalic acids, oxyacids of chlorine, bleaching powder. 
Preparation and properties of the following compounds: Ferrous sulphate, ferric chloride, Mohr's salt, ferric oxide, copper sulphate, oxide and sulphate of zinc. 
Principles of qualitative analysis:

 Group I to V excluding interfering radicals. 
Ores and minerals:

Commonly occurring ores of iron, copper, lead, magnesium and aluminium. 

 

Organic Chemistry: -

Basic structure of organic compounds: -

Polarity and inductive effects in alkyl halides. Reactive intermediates produced during homolytic and heterolytic bond cleavage. Formation, structure and stability of Alkyl carbocations and free radicals. 
About Alkanes:-

Physical properties of alkanes (mp, bp and density), combustion and halogenation of alkanes. Preparation of alkanes by Wurtz coupling and decarboxylation reaction. 
Structure and physical properties of alkenes and alkynes (bp, density, dipole moment), acidity of alkynes. Preparation of alkenes and alkynes by elimination reaction. Electrophilic addition reaction of alkenes with Br2 HBr, HOCl. Reactions of alkynes: Metal acetylides. 
Benzene: structure and aromaticity. Electrophilic substitution reactions; bromination, nitration, sulfonation (orientation excluded). Phenols: acidity, electrophilic reaction (halogenation, nitration and sulphonation). 
Characteristic reactions of the followings: Alcohol (esterification, dehydration and oxidation). Reaction of alcohols with sodium, phosphorous halides, ZnCl2/Conc. HCl. Alkyl halides (nucleophilic substitution reactions). Aldehydes and ketones (oxidation, reduction, oxime and hydrazone formation). Carboxylic acids (formation of esters, acid chlorides and amides).

 

 

 

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